项勇刚,男,教授,理学博士,博士研究生导师,邮箱: ygxiang@mail.hzau.edu.cn,QQ:75459708。获2019年研究生指导教师“教书育人奖”,武汉市东湖高新区第十批 “3551光谷人才计划-创新(短期)人才”等荣誉称号,担任扬州市高新区科技镇长团成员。教学上,承担了本科生《有机化学》/《有机化学A》/《有机化学B》、研究生《现代化学进展》/《有机合成(双语)》等课程。科研上,主要围绕新型共价有机框架(COFs)的设计、合成及其光电性能展开理论及应用研究。首次合成了非取代喹啉桥连COFs,并发展了一种连续后修饰策略将亚胺桥联COFs转变为恶唑桥连COFs的普适性策略等,极大拓展了这类芳香杂环桥联COFs体系在光电转化中的应用。自2014年入职以来,以第一作者或通讯作者在Angew. Chem. Int. Ed., Chem. Sci., ACS Energy Lett.等刊物上发表SCI论文20多篇;获批国家自然科学基金面上项目2项、青年科学基金项目1项、校企合作项目多项、“3551光谷人才计划”1项等。
所属课题组:有机光电材料实验室
教育背景
2009.07-2013.04 德国马堡大学,有机化学,博士,导师:Eric Meggers 教授
2005.09-2009.06 厦门大学,有机化学,理学硕士,导师:黄培强 教授
2001.09-2005.06 华中农业大学,应用化学,理学学士
工作背景
2023.07-至今 华中农业大学,化学学院,教授
2020.11-2023.06 华中农业大学,理学院化学系,教授
2014.06-2020.11 华中农业大学,理学院化学系,副研究员
2017.09-2018.06 清华大学,访问学者,合作导师:朱永法 教授
研究领域:新型共价有机框架(COFs)的设计、合成及光电性能研究
承担项目及人才计划
1. 国家自然科学基金面上项目,亚胺键锁定为芳香杂环桥:高稳定有机框架构建及其光催化性能研究,22475078,2025.01-2028.12,50万,主持。在研。
2. 校企合作。湖北新业烟草薄片开发有限公司项目技术(研究)开发项目,2023.03-2024.10,68万,主持。在研。
3. 国家自然科学基金面上项目,基于活性位点及质子耦合电子转移调控提升D-A共价有机框架光催化制氢研究,21975090,2020.01-2023.12,65万,主持。已结题。
4. 国家自然科学基金青年科学基金项目,基于能级优化及界面力增强协同提升D-A共轭聚合物基复合材料可见光催化制氢性能研究,51802107,2019.01-2021.12,26万,主持,已结题。
5. 武汉市东湖高新区第十批 “3551光谷人才计划” “创新(短期)人才”项目,2017.12-2020.11,主持,已结题。
6. 湖北省环境监测站的横向项目“环境监测科研课题研究合作项目”,5万,2017.9-2018.12,主持,已结题。
7. 校自主科技创新基金学科交叉研究专项,共轭微孔聚合物-TiO2异质结复合材料的制备及其光催化降解农药的构效关系,2662017JC021,2017.01-2019.12,24万,主持,已结题。
8. 校自主科技创新基金青年教师科技创新专项,无机半导体材料光催化有机反应”,2662015QC036,2015.01-2016.12,8万元,主持,已结题。
9. 中央高校基本科业务费专项资金“基于DNA为模板的发色团分子聚集”,2014BQ061,2014.09-2016.12,15万,主持,已结题。
学术成果
加入华中农业大学后第一作者及通讯作者论文:
1. Yanqiu Zhu, Dekang Huang, Wanqin Wang, Gang Liu, Chizhu Ding*, Yonggang Xiang*. Sequential Oxidation/Cyclization of Readily Available Imine Linkages to Access Benzoxazole-linked Covalent Organic Frameworks. Angew. Chem. Int. Ed. 2024, e202319909
2. Huaji Pang, Dekang Huang*, Gang Liu, Yanqiu Zhu, Xiaodong Zhao, Wanqin Wang, Yonggang Xiang*. Embedding Hydrogen Atom Transfer Moieties in Covalent Organic Frameworks for Efficient Photocatalytic C–H Functionalization. Angew. Chem. Int. Ed. 2023, 62, e202313520.
3. Wanqin Wang#, Dekang Huang#, Wenlong Zheng, Xiaodong Zhao, Kuanxiao He, Dekang Huang, Yonggang Xiang*. Construction of Amide-Linked Covalent Organic Frameworks by N-Heterocyclic Carbene-Mediated Selective Oxidation for Photocatalytic Dehalogenation. Chem. Mater. 2023, 35, 7154-7163.
4. Huaji Pang, Dekang Huang, Yanqiu Zhu, Xiaodong Zhao, Yonggang Xiang*. One-pot cascade construction of nonsubstituted quinoline-bridged covalent organic frameworks. Chem. Sci. 2023, 1543-1550.
5. Lijuan Fu, Dekang Huang*, Jiahe Peng, Neng Li*, Zonghao Liu, Yan Shen, Xiaodong Zhao, Yankai Gua, Yonggang Xiang*. Charge redistribution in covalent organic frameworks via linkage conversion enables enhanced selective reduction of oxygen to H2O2. J. Mater. Chem. A 2023, 11, 18945-18952.
6. Xiaodong Zhao, Huaji Pang, Dekang Huang, Gang Liu, Jianxiang Hu, Yonggang Xiang*. Construction of Ultrastable Nonsubstituted Quinoline-Bridged Covalent Organic Frameworks via Rhodium-Catalyzed Dehydrogenative Annulation. Angew. Chem. Int. Ed. 2022, e20220883.
7. Xiaodong Zhao, Bo Chen, Wenbo Dong, Shengyao Wang, Yonggang Xiang*, Hao Chen*. Two consecutive post-synthetic modifications of benzothiadiazole-based conjugated polymers for enhanced photocatalytic H2 evolution: the significance of the sulfinyl group. J. Mater. Chem. A 2021, 9, 10208-10216.
8. Wenbo Dong, Yi Yang, Yonggang Xiang*, Shengyao Wang, Pei Wang, Jianxiang Hu, Li Rao*, Hao Chen*. A highly stable all-in-one photocatalyst for aryl etherification: the NiII embedded covalent organic framework. Green Chem. 2021, 23, 5797-5805.
9. Yonggang Xiang, Wenbo Dong, Pei Wang, Shengyao Wang*, Xing Ding, Fumihiko Ichihara, Zhuan Wang, Yoshiki Wada, Shangbin Jin, Yuxiang Weng, Hao Chen*, Jinhua Ye*. Constructing electron delocalization channels in covalent organic frameworks powering CO2 photoreduction in water. Appl. Catal., B: Environ. 2020, 274, 119096.
10. Bo Chen, Nan Yang, Xuepeng Wang, Yonggang Xiang*, Hao Chen*. Post-side chain engineering of difluorinated benzothiadiazole-based conjugated microporous polymer for enhanced photocatalytic H2 evolution. Appl. Surf. Sci. 2020, 499, 143865.
11. Xuepeng Wang, Xiaodong Zhao, Wenbo Dong, Xiaohu Zhang, Yonggang Xiang*, Qiaoyun Huang, Hao Chen*. Integrating amino groups within conjugated microporous polymers by versatile thiol–yne coupling for light-driven hydrogen evolution. J. Mater. Chem. A 2019, 7, 16277-16284.
12. Bo Chen, Xuepeng Wang, Wenbo Dong, Xiaohu Zhang, Li Rao, Hao Chen, Dekang Huang*, Yonggang Xiang*. Enhanced Light-Driven Hydrogen-Production Activity Induced by Accelerated Interfacial Charge Transfer in Donor–Acceptor Conjugated Polymers/TiO2 Hybrid. Chem-Eur J 2019, 25, 3362-3368.
13. Xuepeng Wang, Bo Chen, Wenbo Dong, Xiaohu Zhang, Zibiao Li, Yonggang Xiang*, Hao Chen*. Hydrophilicity-Controlled Conjugated Microporous Polymers for Enhanced Visible-Light-Driven Photocatalytic H2 Evolution. Macromol. Rapid Commun. 2018, e1800494.
14. Yonggang Xiang#, Xuepeng Wang#, Li Rao, Pei Wang, Dekang Huang, Xing Ding, Xiaohu Zhang, Shengyao Wang, Hao Chen*, Yongfa Zhu*. Conjugated Polymers with Sequential Fluorination for Enhanced Photocatalytic H2 Evolution via Proton-Coupled Electron Transfer. ACS Energy Letters 2018, 3, 2544-2549.
15. Yonggang Xiang, Xuepeng Wang, Xiaohu Zhang, Huijie Hou, Ke Dai, Qiaoyun Huang, Hao Chen*. Enhanced Visible Light Photocatalytic Activity of TiO2 Assisted by Organic Semiconductors: A Structure Optimization Strategy of Conjugated Polymers. J. Mater. Chem. A. 2018, 6, 153-159.
16. Yonggang Xiang, Xiaohu Zhang, Xuepeng Wang, Xing Ding, Dekang Huang, Hao Chen*. Molecular structure design of conjugated microporous poly(dibenzo[b,d]thiophene 5,5-dioxide) for optimized photocatalytic NO removal. J. Catal. 2018, 357, 188-194.
17. Huijie Hou, Xiaohu Zhang, Dekang Huang, Xing Ding, Shengyao Wang, Xianglong Yang, Shengqing Li, Yonggang Xiang*, Hao Chen*. Conjugated Microporous Poly(benzothiadiazole)/TiO2 Heterojunction for Visible-Light-Driven H2 Production and Pollutant Removal. Appl. Catal. B: Environ. 2017, 203, 563-571.
18. Shengyao Wang, Xianglong Yang, Huijie Hou, Xing Ding, Shenhui Li, Feng Deng, Yonggang Xiang*, Hao Chen*. Highly efficient visible light induced photocatalytic activity of a novel in situ synthesized conjugated microporous poly(benzothiadiazole)-C3N4 composite. Catal. Sci. Technol. 2017, 7, 418-426.
19. Xiaohu Zhang#, Xuepeng Wang#, Jie Xiao, Shengyao Wang, Dekang Huang, Xing Ding, Yonggang Xiang*, Hao Chen*. Synthesis of 1,4-Diethynylbenzene-Based Conjugated Polymer Photocatalysts and Their Enhanced Visible/Near-Infrared-Light-Driven Hydrogen Production Activity. J. Catal. 2017, 350, 64-71.
20. Yonggang Xiang#, Ma Nwe Nwe Linn Oo#, Zibiao Li*, Xian Jun Loh*. Recent development of synthetic nonviral systems for sustained gene delivery. Drug Discovery Today 2017, 22, 1318-1335.
21. Xianglong Yang#, Yonggang Xiang#, Yang Qu, Xing Ding, Hao Chen*. Novel in situ fabrication of conjugated microporous poly(benzothiadiazole)-Bi2MoO6 Z-scheme heterojunction with enhanced visible light photocatalytic activity. J. Catal. 2017, 345, 319-328.
22. Yonggang Xiang, Qingye Zhang, Zibiao Li*, Hao Chen*. Role of electrostatic complementarity between perylenediimide and porphyrin in highly stabilized GNA. Mater. Sci. Eng., C. 2017, 70, 1156-1162.
已出版专著章节
Yonggang Xiang*, Zibiao Li, Chapter 3 of “Functional Materials from Lignin: Methods and Advances“, World Scientific Pub Co Inc, 2018.
学术成果主页:http://www.scholarmate.com/psnweb/homepage/show